Stereochemistry of addition of vinylacetylene to C2-epimeric trans -2-methyldecahydro-4-quinolones and trans-1,2-dimethyldecahydro-4-quinolones |
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| Authors: | A. A. Akhrem L. I. Ukhova A. P. Marochkin G. V. Bludova |
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| Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR;(2) Institute of Physical and Organic Chemistry, Academy of Sciences of the Belorussian SSR, USSR |
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| Abstract: | Conclusions A study was made of the stereochemistry of the addition of vinylacetylene and butylmagnesium halide to the trans-2-methyl- and trans-1,2-dimethyldecahydro-4-quinolones, and the conformations of the vinyl-acetylenic and butyl-substituted alcohols of the decahydroquinoline series that are formed here were established.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2257–2263, October, 1972.n |
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