Dissociation constants of organophosphinic acid compounds |
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| Authors: | Martinez M Miralles N Sastre A Bosch E |
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| Affiliation: | Chemical Engineering Department, Universitat Politècnica de Catalunya, E.T.S.E.I.B., Avda. Diagonal 647, Barcelona, Spain. |
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| Abstract: | The dissociation equilibria of di(2,4,4-trimethylpentyi) phosphinic acid, mono(2,4,4-trimethylpentyl) phosphinic acid, di(n-octyl)phosphinic acid and mono(n-octyl)phosphinic acid have been studied in ethanol-water mixtures by potentiometric titration at 25 degrees C. These data have been analysed both graphically numerically using the program LETAGROP-ZETA. The obtained pK(a) values have been correlated with the corresponding values in water, determined both indirectly by means of extraction measurements and by estimation using the suitable Hammett equation. |
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