Determination of absolute configurations from vibrational raman optical activity: (trans)-2,3-dimethylthiirane |
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| Authors: | Polavarapu P L Pickard S T Smith H E Black T M Barron L D Hecht L |
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| Institution: | Department of Chemistry, Vanderbilt University, Nashville, TN 37235, USA. |
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| Abstract: | Experimental and theoretical vibrational Raman optical activity (VROA) spectra of (2R,3R)-2,3-dimethylthiirane in the 200-1500 cm(-1) region are presented. The level of agreement obtained for the observed and predicted VROA signs suggests that the absolute configurations of chiral molecules can be determined confidently using VROA. |
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