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Expedient copper-catalyzed borylation reactions using amino acids as ligands |
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| Authors: | Meng-Yan Liu;Shi-Bin Hong;Wei Zhang;Wei Deng;Research Center of Nano Science and Technology Shanghai University; |
| Institution: | a Research Center of Nano Science and Technology, Shanghai University, Shanghai 200444, China; b School of Chemical and Engineering, Shanghai Institute of Technology, Shanghai 201418, China |
| Abstract: | Amino acids were found to be as good ligands for copper-catalyzed borylation reactions of primary and secondary alkyl halides, and the B2pin2 acted as bi-boron source for borylation. The high reaction efficiency and mild conditions make the new catalyst system a useful alternative to the recently developed methods for the preparation of alkylboronic esters. |
| Keywords: | Cu-catalyzed Borylation Amino acid Alkylboronic Organoboron |
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