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Synthesis and molecular structure oftrans-2,6-dimethallyl-1,1-dimethyl-1,2,3,6-tetrahydropyridinium iodide
Authors:Yu. N. Bubnov  E. E. Demina  M. O. Dekaprilevich  Yu. T. Struchkov
Affiliation:(1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation
Abstract:The structure oftrans-2,6-dimethallyl-1,1-dimethyl-1,2,3,6-tetrahydropyridinium iodide was established by X-ray structural analysis. The corresponding base was synthesized by reductive diallylation of pyridine with trimethallylborane in the presence of 2-propanol. Deceased in 1995. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1413–1415, July, 1997.
Keywords:allylboration  pyridine  trimethallylborane   trans-2,6-dimethallyl-1,2,3,6-tetrahydropyridine  X-ray structural analysis
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