Synthesis and molecular structure oftrans-2,6-dimethallyl-1,1-dimethyl-1,2,3,6-tetrahydropyridinium iodide |
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Authors: | Yu. N. Bubnov E. E. Demina M. O. Dekaprilevich Yu. T. Struchkov |
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Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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Abstract: | The structure oftrans-2,6-dimethallyl-1,1-dimethyl-1,2,3,6-tetrahydropyridinium iodide was established by X-ray structural analysis. The corresponding base was synthesized by reductive diallylation of pyridine with trimethallylborane in the presence of 2-propanol. Deceased in 1995. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1413–1415, July, 1997. |
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Keywords: | allylboration pyridine trimethallylborane trans-2,6-dimethallyl-1,2,3,6-tetrahydropyridine X-ray structural analysis |
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