| Synthesis and Structural Characterization of Manganese Carbonyl Incorporated Polyoxomolybdate （n-Bu4N）2 [Mo6O16（OCH3）2 {HOCH2C（CH2O）3}2 {Mn（CO）3}2] |
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| 作者姓名： | WANG Jing-ping LI Ji-li NIU Jing-yang |
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| 作者单位： | Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, P R. China |
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| 基金项目： | Supported by the National Natural Science Foundation of China（No.20771034）, Program for New Century Excellent Talents in University of Henan Province, China（No.005HANCET-02） and the Natural Science Foundation of Henan Province, China （No.0611020200）. |
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| 摘 要： | The polyoxoanion incorporated {Mn（CO）3^＋} complex, （n-Bu4N）2Mo6O16（OCH3）2{HOCH2C（CH2O）3}2·{Mn（CO）3}2]（1）, has been synthesized by the reaction of （n-Bu4N）4Mo8O26] with Mn（CO）5Br in methanol, in the presence of C（CH2OH）4. The complex 1 has been characterized by IR, UV-Vis, X-ray single crystal diffraction, and TG. Crystal data for the complex 1：C25H48MnMo3NO16 （1）, Triclinic Pi, a=0.9405（3） nm, b=1.3351（4） nm, c=1.5455（4） nm, α=103.206（5）°, β=102.165（5）°, γ=100.784（5）°, V=1.7896（9） nm^3, Z=2, R1=0.0703, wR2= 0.1495. The structure analysis of complex 1 shows that the complex consists of two tetrabutylammonium cations and a polyoxomolybdate anion that incorporates two fac-Mn（CO）3^＋ units. The anion of complex 1 can be considered as the dimer of two rhomb-like anions by sharing of two comers.
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| 关 键 词： | 锰 钼酸盐 碳酰基 结构特性 |
| 收稿时间： | 7 March 2008 |
Synthesis and Structural Characterization of Manganese Carbonyl Incorporated Polyoxomolybdate (n-Bu4N)2[Mo6O16(OCH3)2{HOCH2C(CH2O)3}2{Mn(CO)3}2] |
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| WANG Jing-ping LI Ji-li NIU Jing-yang.Synthesis and Structural Characterization of Manganese Carbonyl Incorporated Polyoxomolybdate (n-Bu4N)2[Mo6O16(OCH3)2{HOCH2C(CH2O)3}2{Mn(CO)3}2][J].Chemical Research in Chinese University,2008,24(6):675-678. |
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| Authors: | Jing-ping WANG Ji-li LI Jing-yang NIU |
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| Institution: | aInstitute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, P. R. China |
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| Abstract: | Polyoxomolybdate Manganese Carbonyl |
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| Keywords: | Polyoxomolybdate Manganese Carbonyl |
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