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| CRYSTAL STRUCTURE AND SHG EFFECT OF COMPLEX [Zn(POM)_2Br_2] | |
| 摘 要： | [Zn(POM)_2Br_2](POM is 3-Methyl-4-Nitropyridine-1-Oxide),C_(12)H_(12)Br_2N_4O_6Zn,Mr=533.44,triclinic,P1,a=11.450(3),b=13.027(2),c=6.605(1),α=101.25(1),β=96.96(2),γ=108.06(2)°,V=901.2(4)~3,Z=2,D_c=1.97g·cm~(-3),(MoK_α)=0.71069,F(000)=520,μ=58.21cm~(-1),final R=0.040 for 2192 observed reflections,T=296K.The compound is amononuclear complex,containing a tetrahedrally coordinated zinc atom. |
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