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A new solvent system for the separation of Th4+, UO 2 2+ and Zr4+ in the presence of common anions by thin-layer chromatography
Authors:A Mohammad  N Fatima
Institution:(1) Chemistry Section, Z.H. College of Engineering and Technology, Aligarh Muslim University, 202 002 Aligarh, India
Abstract:Summary A TLC method has been developed for separating Th4+, UO2 2+ and Zr4+ in the presence of some common anions using a dimethylamine/acetone/formic acid mobile phase. Capacity factors, separation factors and resolution for the separation of Th4+ from UO2 2+ have been evaluated. The effect of the pH of the sample on RF values of Th4+, UO2 2+, Ni2+ and Cu2+ has also been examined.
Keywords:Thin-layer chromatography  Th4+  UO          2          2+            Zr4+ separation  Dimethylamine/acetone/formic acid eluent
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