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Deposition features of Ni on self-assembled microtubule template from biolipid by electroless method
引用本文:FU Yubin1,2,ZHANG Lide1,ZHENG Jiyong2,FU Shangang3 & ZHU Mingwei3 1. Institute of Solid State Physics,Chinese Academy of Sciences,Hefei 230031,China, 2. Luoyang Ship Material Research Institute,Luoyang 471039,China, 3. College of Life Science,Henan Normal University,Xinxiang 453002,China. Deposition features of Ni on self-assembled microtubule template from biolipid by electroless method[J]. 中国科学B辑(英文版), 2004, 47(3): 228-234. DOI: 10.1360/03yb0131
作者姓名:FU Yubin1  2  ZHANG Lide1  ZHENG Jiyong2  FU Shangang3 & ZHU Mingwei3 1. Institute of Solid State Physics  Chinese Academy of Sciences  Hefei 230031  China   2. Luoyang Ship Material Research Institute  Luoyang 471039  China   3. College of Life Science  Henan Normal University  Xinxiang 453002  China
作者单位:FU Yubin1,2,ZHANG Lide1,ZHENG Jiyong2,FU Shangang3 & ZHU Mingwei3 1. Institute of Solid State Physics,Chinese Academy of Sciences,Hefei 230031,China; 2. Luoyang Ship Material Research Institute,Luoyang 471039,China; 3. College of Life Science,Henan Normal University,Xinxiang 453002,China
摘    要:The self-assembly of lipid molecules is in close relationship with the structure and function of a cell membrane. A cell membrane has a variety of lipid molecules. Lipid molecules have their amphiphile na-tures, and their self-assembly can form a variety of thermodynamically stable microstructures, such as single-bilayer or multi-bilayer spherical and ellipsoidal liposome, microcylindrical and microtubular struc-tures[1]. These microstructures exhibit different bio-logical functions in living …

收稿时间:2007-10-31

Deposition features of Ni on self-assembled microtubule template from biolipid by electroless method
FU Yubin,Zhang Lide,Zheng Jiyong,FU Shangang,ZHU Mingwei. Deposition features of Ni on self-assembled microtubule template from biolipid by electroless method[J]. Science in China(Chemistry), 2004, 47(3): 228-234. DOI: 10.1360/03yb0131
Authors:FU Yubin  Zhang Lide  Zheng Jiyong  FU Shangang  ZHU Mingwei
Affiliation:1. Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China;Luoyang Ship Material Research Institute, Luoyang 471039, China
2. Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China
3. Luoyang Ship Material Research Institute, Luoyang 471039, China
4. College of Life Science, Henan Normal University, Xinxiang 453002, China
Abstract:Diacetylenic glycero-phosphatidylcholine is a chiral molecule with amphiphilic property, and it can self-assembly into a lipid microtubular structure. The lipid microtubule is a stable structure formed by tightly wound helical ribbons, and the ribbon-wrapping patterns have a significant effect on their chemical deposition on the microtubules. The deposition of colloidal Pd catalyst occurs mainly on the helical edge of the wound helical ribbons to form helical deposition lines of colloidal Pd particles in the interior and exterior of the lipid microtubules, resulting in an uneven chemical deposition of Ni on the microtubules. Catalyzed by as-deposited colloidal Pd, metallized Ni microtubules are characterized by a helical form, which may be in relation to inner stress due to the thickness difference or the different deposition processes. The observation of microtom shows that metallized tubules have a hollow structure. Some metallized tubules have a kind of coaxial double layer structure observed in the direct experiment evidence, indicating that metallization can occur in the inner and outer surface of the lipid tubules. Both lipid microtubules and metallized microtubules can be used as vehicles for encapsulating biological active mole-cules to control their release and to develop micro-components in biological and mechanical systems.
Keywords:molecular self-assembly   lipid microtubules   helical pattern   site-specific deposition   electroless metallization.
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