Proton-acceptor properties of azahomofullerene and fullerenoaziridine containing a cyanuric acid fragment |
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| Authors: | I P Romanova O A Larionova A A Balandina Sh K Latypov A R Mustafina V V Skripacheva V V Zverev O G Sinyashin |
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| Institution: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia |
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| Abstract: | 13C and 1H NMR and UV spectral studies on 1,3-diallyl-5-4-(azahomo60]fullereno)butyl]hexahydro-1,3,5-triazine-2,4,6-trione (5,6]-open isomer) and 1,3-diallyl-5-4-(aziridino60]fullereno)butyl]hexahydro-1,3,5-triazine-2,4,6-trione (6,6]-closed isomer), as well as quantum-chemical calculations, showed that only the latter possesses weakly basic properties. |
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