Asymmetric synthesis of beta-lactams using chiral-memory effect on photochemical gamma-hydrogen abstraction by thiocarbonyl group |
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| Authors: | Sakamoto Masami Kawanishi Hiroya Mino Takashi Fujita Tsutomu |
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| Affiliation: | Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan. sakamotom@faculty.chiba-u.jp |
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| Abstract: | Optically active beta-lactams were synthesized via photochemical intramolecular gamma-hydrogen abstraction reaction of thioimides involving a highly-controlled chiral-memory effect. |
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