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Synthesis and characterization of 5-octylthieno[3,4-c]pyrrole-4,6-dione derivatives as new monomers for conjugated copolymers
Authors:Berrouard Philippe  Grenier François  Pouliot Jean-Rémi  Gagnon Eric  Tessier Christian  Leclerc Mario
Affiliation:Canada Research Chair on Electroactive and Photoactive Polymers, De?partement de Chimie, Universite? Laval, Que?bec City, Que?bec, G1K 7P4, Canada.
Abstract:An efficient route for the synthesis of 1-iodo-5-octyl-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione as a key intermediate to build new electron-deficient monomers and related conjugated polymers is reported. Along these lines, two new low bandgap copolymers were synthesized from Stille or Suzuki coupling. These polymers were characterized and their properties compared to those of analogous conjugated polymers.
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