Synthesis and Structure of [Fe3O(O2CCH2OMe)6(H2O)3][FeCl4] |
| |
Authors: | Douglas Ogrin Andrew R. Barron |
| |
Affiliation: | (1) Department of Chemistry, Rice University, 6100 Main Street, Houston, TX 77005, USA |
| |
Abstract: | Abstract The structure of [Fe3O(O2CCH2OMe)6(H2O)3][FeCl4] · 2.5H2O has been determined. The three iron atoms and the μ3-oxo are coplanar. Each carboxylic ligand is bidentate and links two iron atoms in the cluster. The clusters are linked by intra-trimer hydrogen bonding to form a zigzag motif that forms sheets via hydrogen bonding involving disordered waters of hydration. The [FeCl4]− anion is intercalated between the hydrogen-bonded sheets. Crystal data: space group P21/n, a = 10.276(2), b = 22.793(5), c = 17.091(3) ?, β = 96.66(3)°, V = 3976(1) ?3, Z = 4, R = 0.0837, wR 2 = 0.1836. Graphical Abstract The structure of [Fe3O(O2CCH2OMe)6(H2O)3][FeCl4] · 2.5H2O has been determined in which the clusters are linked by intra-trimer hydrogen bonding to form a zigzag motif that forms sheets via hydrogen bonding involving disordered waters of hydration. |
| |
Keywords: | Iron Carboxylate Oxo Trimer Sheet Zigzag |
本文献已被 SpringerLink 等数据库收录! |
|