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Is the percolation transition of hard spheres a thermodynamic phase transition?
Authors:Karl W Kratky
Institution:(1) Institut für Experimentalphysik der Universität Wien, A-1090 Vienna, Austria
Abstract:In hard-sphere systems, there is a fluid-solid transition, but no gas-liquid transition. In the fluid region, however, one can find a purely geometric percolation transition, which is studied in detail. The van der Waals model of hard spheres is treated. In this model, a uniform negative background potential is added. This modification does not change the structure, but induces a gas-liquid transition. In fact, percolation and the gas-liquid transition can be related to each other.
Keywords:Statistical mechanics  phase transitions  percolation  hard spheres  extended spheres  van der Waals model
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