| 联萘衍生物作为手性配体在二烷基锌和醛不对称加成反应中的应用 |
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| 引用本文： | 刘旭东,丁孟贤,高连勋. 联萘衍生物作为手性配体在二烷基锌和醛不对称加成反应中的应用[J]. 有机化学, 2004, 24(7): 728-744,J001 |
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| 作者姓名： | 刘旭东 丁孟贤 高连勋 |
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| 作者单位： | 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室,长春,130022 |
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| 摘 要： | 光学活性的联萘衍生物作为优异的手性配体应用到不对称催化中已取得了巨大进展,显示出广阔的应用前景,综述了近年来联萘衍生物小分子、树枝状大分子和高分子作为手性配体和其金属络合物作为手性催化剂在二烷基锌和醛不对称加成反应中的应用.
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| 关 键 词： | 小对称加成 手性配体 金属络合物 催化 |
Application of Binaphthyl Derivatives as Chiral Ligands in Asymmetric Dialkylzinc Additions to Aldehydes |
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| LIU,Xu-Dong DING,Meng-Xian GAO,Lian-Xun. Application of Binaphthyl Derivatives as Chiral Ligands in Asymmetric Dialkylzinc Additions to Aldehydes[J]. Chinese Journal of Organic Chemistry, 2004, 24(7): 728-744,J001 |
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| Authors: | LIU Xu-Dong DING Meng-Xian GAO Lian-Xun |
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| Abstract: | Optically active binaphthyl derivatives have been extensively used as excellent chiral ligands in asymmetric catalytic reaction. This review describes recent advances in the application of monomeric, dendrimeric and polymeric binaphthyl derivatives and their metal complexes as chiral catalysts in asymmetric dialkylzinc additions to aldehydes. |
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| Keywords: | asymmetric addition chiral ligand metal complex catalysis |
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