(1) Faculty of Chemistry, A. Mickiewicz University, 60-780 Poznan, Poland;(2) Laboratoire Catalyse et Spectrochimie-URA CNRS 0414, ISMRA-UNIVERSITÉ-6, Boulevard du Maréchal Juin, 14050 Caen Cedex, France
Abstract:
Adsorption of CH3SH and CH3OH on activated NaX and NaY zeolites has been studied by IR spectroscopy. Only NaX is able to provoke the dissociative adsorption of CH3SH at room temperature and that of CH3OH at 623 K. Results are discussed taking into account sodium cations in the SIII position.