Tetraplatinum precursors for supramolecular assemblies: syntheses, crystal structures, and stereoselective self-assemblies of [Pt4(micro-OCOCH3)6(kappa4-N4-DArBp)] (DArBp = 1,3-bis(arylbenzamidinate)propane) |
| |
Authors: | Ohashi Masato Yagyu Akihiro Yamagata Tsuneaki Mashima Kazushi |
| |
Institution: | Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka, 560-8531, Japan. |
| |
Abstract: | Treatment of the cisoid-capped complex Pt(4)(micro-OCOCH(3))(6)(kappa(4)-N(4)-DAr'Bp)] (), which was obtained from the reaction of Pt(4)(micro-OCOCH(3))(8)] (1) with Na(2)D(t)BuPhBp (D(t)BuPhBp = 1,3-bis(para-tert-butylphenylbenzamidinate)propane), with an equimolar amount of 1,1'-ferrocenedicarboxylic acid undergoes a stereoselective self-assembly to afford an indented-quadrangle tetramer Pt(4)(micro-OCOCH(3))(4)(kappa(4)-N(4)-D(t)BuPhBp){Fe(C(5)H(4)COO)(2)}](4) as a single diastereomer. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|