Determination of sulfonylurea herbicides in water using solid-phase extraction followed by liquid chromatography with electrospray ion trap mass spectrometry |
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Authors: | Xihui Ouyang Wei Zhang Jun Xu Na Chang Canping Pan Jingping Zhang Weimin Niu |
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Institution: | 1.Department of Applied Chemistry, College of Science,China Agriculture University,Beijing,China;2.Wuxi Municipal Center for Disease Control and Prevention,Wuxi,China |
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Abstract: | A method has been developed for confirmation and quantitation of ten sulfonylurea herbicides (nicosufuron, thifensulfuron-methyl,
metsulfuron-methyl, sulfometuron-methyl, chlorsulfuron, ethametsulfuron-methyl, tribenuron, bensulfuron-methyl, pyrazosulfuron-ethyl
and chlorimuron-ethyl) in water samples. Herbicides were extracted from water by off-line solid-phase extraction (SPE). Different
types of absorbents were evaluated: silica-based ODS-C18 and two polymeric sorbents, Cleanert HXN and Oasis HLB. Analyte determination and quantitation was performed by liquid chromatography
with electrospray mass spectrometry (LC-ESI-MS) instrumentation, equipped with ion trap mass filter. Confirmatory analysis was carried out by LC/MS/MS. MS data acquisition
was performed by a single or two-ion extracted ion monitoring program. The ten herbicides were measured in fortified tap water.
Average recoveries of the nine analytes (except for tribenuron) from water samples were in the range of 77–109%, and the RSD
ranged from 0.3 to 14.5%. The limit of detections (LODs) varied from 6 to 34.8 ng/L. |
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