Unprecedented asymmetric induction through configurationally stable lithium N-(alpha-methylbenzyl)phosphinamides. A new entry to enantiomerically pure gamma-aminophosphinic acids and esters |
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| Authors: | Fernández Ignacio Gómez Gloria Ruiz Alfonso Ignacio Iglesias María J Ortiz Fernando López |
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| Institution: | Area de Química Orgánica, Universidad de Almería, Carretera de Sacramento, 04120, Almería, Spain. |
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| Abstract: | The first examples of configurationally stable N-benzyl-N-phosphinoyl carbanions are described. Their applications to the synthesis of homochiral gamma-aminophosphinic acids and esters via highly enantioselective dearomatising reactions are shown. |
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