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Highly enantioselective transfer hydrogenation of alpha,beta-unsaturated ketones
Authors:Martin Nolwenn J A  List Benjamin
Affiliation:Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim an der Ruhr, Germany.
Abstract:We describe an efficient and highly enantioselective conjugate transfer hydrogenation of alpha,beta-unsaturated ketones that is catalyzed by a salt made from tert-butyl valinate and a recently introduced powerful chiral phosphoric acid catalyst (TRIP).
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