Highly enantioselective transfer hydrogenation of alpha,beta-unsaturated ketones |
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Authors: | Martin Nolwenn J A List Benjamin |
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Affiliation: | Max-Planck-Institut für Kohlenforschung, D-45470 Mülheim an der Ruhr, Germany. |
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Abstract: | We describe an efficient and highly enantioselective conjugate transfer hydrogenation of alpha,beta-unsaturated ketones that is catalyzed by a salt made from tert-butyl valinate and a recently introduced powerful chiral phosphoric acid catalyst (TRIP). |
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