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Investigation on poly[(methylsilylene ethynylene phenylene ethynylene)-co-(tetramethyldisiloxane ethynylene phenylene ethynylene)]
Authors:Fei Gao  Ling Ling Zhang  Fa Rong Huang  Lei Du Key Laboratory for Specially Functional Polymeric Materials  Related Technology of the Ministry of Education  East China University of Science  Technology  Shanghai  China
Institution:Key Laboratory for Specially Functional Polymeric Materials and Related Technology of the Ministry of Education, East China University of Science and Technology, Shanghai 200237, China
Abstract:Poly(methylsilylene ethynylene phenylene ethynylene)-co-(tetramethyldisiloxane ethynylene phenylene ethynylene)] was synthesized by polycondensation reaction of m-diethynylbenzene magnesium reagent with 1,3-dichlorotetramethyldisiloxane and dichloromethylsilane. The copolymer was characterized by FT-IR, 1H NMR, differential scanning calorimetry and thermogravi-metric analysis. The results show that the copolymer exhibits good processability and cures at low temperatures. The cured copolymer shows high thermal stability.
Keywords:Silicon-containing arylacetylene resin  Siloxane  m-Diethynylbenzene  Methylsilylene
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