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Salen-based metal-organic frameworks of nickel and the lanthanides
Authors:Roesky Peter W  Bhunia Asamanjoy  Lan Yanhua  Powell Annie K  Kureti Sven
Affiliation:Institut für Anorganische Chemie, Karlsruher Institut für Technologie (KIT), Engesserstr. 15, 76128 Karlsruhe, Germany. roesky@kit.edu
Abstract:A well defined salen-nickel complex was introduced as "metalloligand" in lanthanide-based MOFs. By using this strategy unique structures, in which the salen-nickel unit acts as flexible strut, were obtained. The shape of the network is strongly influenced by the ion radius of the lanthanide element.
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