One-pot synthesis of cyclophane-type macrocycles using manganese(III)-mediated oxidative radical cyclization |
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| Authors: | Ito Yosuke Tomiyasu Yuichi Kawanabe Takahiro Uemura Keisuke Ushimizu Yuu Nishino Hiroshi |
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| Institution: | Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, Kurokami 2-39-1, Kumamoto, 860-8555, Japan. |
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| Abstract: | Cyclophane-type macrocyclic compounds from 21 to 56 members having two fused dihydrofuran rings were synthesized by the manganese(III)-mediated oxidation of terminal dienes with bis(3-oxobutanoate)s containing aromatics. The reaction detail, characterization and reaction pathways are described. |
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