Liquid crystal properties resulting from synergetic effects between non-mesogenic organic molecules and a one nanometre sized octahedral transition metal cluster |
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| Authors: | Mocanu Ana S Amela-Cortes Maria Molard Yann Cîrcu Viorel Cordier Stéphane |
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| Institution: | Université de Rennes 1, UMR Sciences Chimiques de Rennes, UR1-CNRS 6226, Equipe Chimie du Solide et Matériaux, Campus de Beaulieu, CS 74205, 35042 Rennes Cedex, France. |
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| Abstract: | This work presents the synthesis and studies of a red-NIR luminescent liquid crystal compound based on an octahedral metallic cluster core orthogonally bounded to six non-mesogenic organic ligands. It evidences synergetic effects between the organic and inorganic parts of the hybrid, resulting in the generation of liquid crystal properties on cooling from the isotropic melt. |
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