Synthesis and characterization of the hexagonal prismatic cage [THF[subset or is implied by][PhB(CN)(3)](6)[Cp*Rh](6)](6+) |
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| Authors: | Kuhlman Matthew L Yao Haijun Rauchfuss Thomas B |
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| Institution: | Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 6180, USA. |
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| Abstract: | Condensation of Cp*Rh(CH(3)NO(2))(n)](2+) and the tricyanoborate PhB(CN)(3)](-) affords the hexagonal bipyramidal cage PhB(CN)(3)](6)Cp*Rh](6)](6+), demonstrating that tetrahedral tricyanide building blocks can lead to novel cage structures. |
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