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Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts |
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| Authors: | Ismail Awheda Sara J Krivickas Songjie Yang Lee Martin Milena A Guziak Andrew C Brooks Frédéric Pelletier Melvyn Le Kerneau Peter Day Peter N Horton Hiroki Akutsu John D Wallis |
| Institution: | 1. School of Science and Technology, Nottingham Trent University, Clifton Lane, Nottingham NG11 8NS, UK;2. University College London, Department of Chemistry, 20 Gordon Street, London WC1H 0AJ, UK;3. National Crystallography Service, Chemistry Department, University of Southampton, Highfield, Southampton SO17 1BJ, UK;4. Graduate School of Material Science, University of Hyogo, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan |
| Abstract: | The syntheses of a range of enantiopure organosulfur donors with hydrogen bonding groups are described including TTF related materials with two, four, six and eight hydroxyl groups and multiple stereogenic centres and a pair of chiral N-substituted BEDT-TTF acetamides. Three charge transfer salts of enantiopure poly-hydroxy-substituted donors are reported, including a 4:1 salt with the meso stereoisomer of the dinuclear Fe2(oxalate)5]4− anion in which both cation and anion have chiral components linked together by hydrogen bonding, and a semiconducting salt with triiodide. |
| Keywords: | TTF Organosulfur donors Hydrogen bonding Chirality |
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