Catalytic palladium nanoparticles supported on nanoscale MOFs: a highly active catalyst for Suzuki–Miyaura cross-coupling reaction |
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Authors: | Linjie Zhang Zixue Su Feilong Jiang Youfu Zhou Wentao Xu Maochun Hong |
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Institution: | 1. Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;2. University of Chinese Academy of Sciences, Beijing 100049, China |
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Abstract: | Pd nanoparticles have been successfully supported on nanoscale metal-organic frameworks (NMOFs) by using a simple and effective microwave-assisted impregnation process. The resulting composite, representing as a highly active NMOFs supported metal nanoparticles catalyst for the Suzuki cross-coupling reaction between aryl/heteroaryl halides and arylboronic acids, is well characterized, and its high activity and good recyclability are discussed in details. It reveals that, compared to the corresponding bulk MOFs and conventional active carbon materials, nanoscale MOFs as novel support materials for heterogeneous catalysts can exhibit superior performance in the catalytic reactions. |
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Keywords: | Palladium Nanoscale metal-organic frameworks Catalysis Suzuki&ndash Miyaura cross-coupling |
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