The molecular diversity of three-component reactions of 4-dimethylamino- or 4-methoxypyridine with acetylenedicarboxylates and arylidene cyanoacetates |
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Authors: | Jing Sun Dan ZhuHui Gong Chao-Guo Yan |
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Affiliation: | College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, China |
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Abstract: | The three-component reactions of 4-dimethylamino- or 4-methoxypyridine with acetylenedicarboxylates and arylidene cyanoacetates showed very interesting molecular diversity. The polysubstituted 1,8,9,9a-tetrahydro-4H-1,4-ethanoquinolizines, 2H-pyran-2,3-dicarboxylates, and buta-1,3-diene-1,2,4-tricarboxylates derivatives can be formed in high yields and with good diastereoselectivity depending on the substrates and reaction conditions. |
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Keywords: | Multicomponent reaction Diels&ndash Alder reaction Quinolizine 2H-Pyrane Diastereoselectivity |
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