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Copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with CF3CO2Na and elemental sulfur |
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| Authors: | Lijuan Zhai Yaming LiKun Jin Rong ZhangXinmei Fu Chunying Duan |
| Affiliation: | State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China |
| Abstract: | A practical three-component copper-mediated oxidative trifluoromethylthiolation of aryl boronic acids with cheap and readily available sodium trifluoroacetate and elemental sulfur is reported. A variety of trifluoromethylthio-substituted aromatics are synthesized in moderate yields under mild reaction conditions. |
| Keywords: | Copper-mediated Oxidation Trifluoromethylthiolation Sodium trifluoroacetate Synthetic methods |
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