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A convenient two-step synthesis of dialkylphosphate ionic liquids
Authors:Justyna Kotlarska  Koen BinnemansWim Dehaen
Affiliation:Division for Molecular Design and Synthesis, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Box 2404, B-3001 Heverlee, Belgium
Abstract:
Dialkylphosphate ionic liquids are useful solvents for cellulose dissolution and catalytic reactions. In this paper, a new methodology for the synthesis of hydrophobic phosphate-based ionic liquids is described. This method involves the oxidation reaction of an easily prepared H-phosphonate precursor by using the environmentally friendly and inexpensive oxidizing agent hydrogen peroxide.
Keywords:Ionic liquids   Dialkylphosphates   H-phosphonate   Oxidation reactions   Hydrogen peroxide
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