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Iron-catalyzed cross-coupling of aryltrimethylammonium triflates and alkyl Grignard reagents |
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| Authors: | Wang-Jun Guo Zhong-Xia Wang |
| Institution: | Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China |
| Abstract: | Fe(acac)3 effectively catalyzes reaction of aryltrimethylammonium triflates with β-hydrogen-containing primary or secondary alkyl Grignard reagents in a mixed solvent of THF and NMP at room temperature. A series of functional groups are tolerated under the reaction conditions. |
| Keywords: | Aryltrimethylammonium salt C&ndash N activation Alkylation Grignard reagents Iron catalyst Cross-coupling |
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