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超支化/星形聚合物电解质的研究进展
引用本文:任士通,贺丽娟,常贺飞,党小飞,张辽云,李化毅.超支化/星形聚合物电解质的研究进展[J].高分子通报,2012(7):22-34.
作者姓名:任士通  贺丽娟  常贺飞  党小飞  张辽云  李化毅
作者单位:1. 中国科学院研究生院,北京,100049
2. 中国科学院化学研究所,北京分子科学国家实验室,工程塑料重点实验室,北京100190
基金项目:国家自然科学基金资助项目
摘    要:与液体电解质相比较,聚合物电解质以其易加工、设计灵活、质量轻、安全无毒的特点而受到人们的广泛关注,具有取代液态电解质的潜在应用价值,而超支化/星形聚合物以其无定形、低玻璃化转变温度、支化结构等特点可被用于固态电解质。本文综述了超支化/星形聚合物电解质材料的研究进展,重点介绍了超支化/星形聚合物基电解质和超支化/星形聚合物共混基电解质,并对超支化/星形聚合物单一离子导体在锂离子电池方面的应用前景作了概述。

关 键 词:聚合物电解质  超支化聚合物  星形聚合物  锂离子电池

Research Progress in Hyperbranched/Star Polymer Electrolyte
REN Shi-tong,HE Li-juan,CHANG He-fei,DANG Xiao-fei,ZHANG Liao-yun,LI Hua-yi.Research Progress in Hyperbranched/Star Polymer Electrolyte[J].Polymer Bulletin,2012(7):22-34.
Authors:REN Shi-tong  HE Li-juan  CHANG He-fei  DANG Xiao-fei  ZHANG Liao-yun  LI Hua-yi
Institution:1.Graduate University of Chinese Academy of Sciences,Beijing 100049,China; 2.Beijing National Laboratory for Molecular Science,Key Laboratory of Engineering Plastics,Institute of Chemistry, Chinese Academy of Sciences,Beijing 100190,China)
Abstract:Compared with liquid electrolyte,polymer electrolyte has widely attracted researchers’ attention,and has the potential to replace organic liquid electrolyte because of the advantages such as easy processing,flexible design,light weight,safety and non-toxicity.Hyperbranched/star polymer with amorphousness,low glass transition temperature and unique topology has been studied as solid polymer electrolyte.In this review,research progress in hyperbranched/star polymer electrolyte is presented.Special interests are focused on the hyperbranched/star polymer-based electrolytes,hyperbranched/star polymer blend-based electrolyte.Besides,the application of hyperbranched/star polymer-based single ion electrolyte for lithium ion battery is also prospected.
Keywords:Polymer electrolyte  Hyperbranched polymer  Star polymer  Lithium ion battery
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