| 酮烯醇盐的立体选择性氧化二聚反应 |
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| 引用本文： | 匡华,王雅珍.酮烯醇盐的立体选择性氧化二聚反应[J].江苏技术师范学院学报,2006,12(2):13-16. |
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| 作者姓名： | 匡华 王雅珍 |
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| 作者单位： | 江苏技术师范学院化学化工学院 江苏常州213001 |
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| 摘 要： | 综述酮烯醇盐氧化二聚反应的规律,重点是立体选择性的过程;近期进展是利用手性辅助试剂,不对称合成链状和环状的1,4-二羰基化合物。
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| 关 键 词： | 酮 烯醇盐 立体选择性 氧化二聚反应 |
| 收稿时间： | 2006-02-25 |
| 修稿时间： | 2006-04-03 |
Stereoselective Oxidation Dimerization of Ketone Enolates |
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| KUANG Hua, WANG Ya-zhen.Stereoselective Oxidation Dimerization of Ketone Enolates[J].Journal of Jiangsu Teachers University of Technology,2006,12(2):13-16. |
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| Authors: | KUANG Hua WANG Ya-zhen |
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| Institution: | School of Chemistry and Chemical Engineering, Jiangsu Teachers University of Technology, Changzhou 213001, China |
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| Abstract: | This review summarizes the state of the art of the coupling of the enolate of ketones,focusing on the stereoselectivity of the process.Recent developments making use of chiral auxiliaries have put forward the versatility of procedure for the asymmetric synthesis of linear and cyclic 1,4-dicarbonyl compounds. |
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| Keywords: | ketones enolate stereoselectivity oxidative dimerization |
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