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Hydrosilylation of terminal alkynes with alkylidene ruthenium complexes and silanes |
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| Authors: | Menozzi Candice Dalko Peter I Cossy Janine |
| Institution: | ESPCI, 10 rue Vauquelin, 75231-Paris Cedex 05, France. |
| Abstract: | reaction: see text] Ruthenium alkylidene complexes 1-3 mediate hydrosilylation of alkynes with silanes. When triethoxy- or triphenylsilanes are used as silylating agents, the reaction affords alpha-substituted vinylsilanes as major products. |
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