| 本体溶液法合成超高分子量聚苯乙烯 |
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| 引用本文： | 杨第伦,马振田.本体溶液法合成超高分子量聚苯乙烯[J].高等学校化学学报,1995,16(2):312-314. |
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| 作者姓名： | 杨第伦 马振田 |
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| 作者单位： | 中山市应用化学研究所，兰州大学化学系 |
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| 摘 要： | 对２，３－二氰基－２，３－二苯基丁二酸二乙酯引发苯乙烯本体溶液聚合，合成超高分子量聚苯乙烯的宏观动力学进行了研究。结果表明，这种引发剂在苯乙烯中引发聚合性能温和，在一定条件下，随反应时间的增长，聚合产物的分子量不断增高，可形成超高分子量聚合物。
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| 关 键 词： | 二氰基 二苯基 丁二酸二乙酯 聚苯乙烯 聚合 |
Synthesis of Ultra High Molecular Weight Polystyrene by Bulk Solution Polymerization |
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| YANG Di-Lun,JHN Jing,MAZhen-Tian,LIUYou-Cheng.Synthesis of Ultra High Molecular Weight Polystyrene by Bulk Solution Polymerization[J].Chemical Research In Chinese Universities,1995,16(2):312-314. |
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| Authors: | YANG Di-Lun JHN Jing MAZhen-Tian LIUYou-Cheng |
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| Abstract: | The synthesis of ultra high molecular weight polystyrene was carried out by bulk solution polymerization which was initiated with diethy1 2,3-dicyano-2,3-bisphenyl succinate in ethylbenzene.The results indicate that the initiator behaved mildly and that the molecular weight of the polystyrene product increased along with the reaction time. |
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| Keywords: | Diethy1 2 3-dicyano-2 3-bisphenyl succinate Ultra high molecular weight polystyrene Radical polymerization |
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