Total synthesis of amaminol A: establishment of the absolute stereochemistry |
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| Authors: | Kumpulainen Esa T T Koskinen Ari M P Rissanen Kari |
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| Affiliation: | Laboratory of Organic Chemistry, Helsinki University of Technology, P.O. Box 6100, FI-02015 TKK, Espoo, Finland. |
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| Abstract: | ![]()
The first synthetic route to amaminol A with use of an organocatalytic intramolecular Diels-Alder reaction is reported. The absolute stereochemistry is proven with a crystallographic image of a cyclic carbamate of amaminol A. |
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