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Catalysis by titanium (IV) ions of reactions forming chlorohydrins from olefins
Authors:A I Kryukov  S Ya Kuchmii  A V Korzhak
Abstract:A study was made of reactions forming chlorohydrins from cyclohexane and other olefins acted upon by H2O2 and HCl or H2O2 and TiCl4 in alcoholic solutions. The catalyzing action of titanium (1V) was established, and possible reaction mechanisms are discussed.L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prosp. Nauki, 252039, Kiev, Ukraine. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 32, No. 5, pp. 295—299, September–October, 1996. Original article submitted February 9, 1996.
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