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Kinetics of osmium(VIII) catalysis of periodate oxidation of DMF in aqueous alkaline medium

Authors:

Gangadhar H Hugar Sharanappa T Nandibewoor

Institution:

1. P G Department of Studies in Chemistry, Karnatak University, 580 003, Dharwad, India

Abstract:

The osmium(VIII) catalysed IO₄ ⁻ oxidation of DMF in aqueous alkaline medium follows the rate law:

$- {\text{d}}\left {{\text{IO}}_4^ - } \right]/{\text{d}}t = \frac{{kK_2 K_3 {\text{DMF}}]{\text{OH}}^ - ]{\text{Os}}^{{\text{VIII}}} ]_T }}{{1 + K_2 K_3 {\text{DMF}}]{\text{OH}}^ - ] + K_2 {\text{OH}}^ - ]}}$

Keywords:
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