| C60Pt(BINAP)金属配合物的合成表征与光电性能研究 |
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| 引用本文： | 覃世辉,吴振奕,杨绳岩,詹梦熊. C60Pt(BINAP)金属配合物的合成表征与光电性能研究[J]. 无机化学学报, 2008, 24(10): 1626-1630 |
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| 作者姓名： | 覃世辉 吴振奕 杨绳岩 詹梦熊 |
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| 作者单位： | 1. 厦门大学化学化工学院,厦门,361005;广西河池学院化学与生命科学系,宜州,546300
2. 厦门大学化学化工学院,厦门,361005 |
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| 摘 要： | 本文利用配体取代法合成了C60Pt(BINAP)新型富勒烯膦金属配合物,采用质谱、元素分析、紫外.可见吸收光谱、红外吸收光谱、光电子能谱等对该产物进行了表征,并测定了其在光化学电池中的光伏效应.光伏效应测试结果表明:在BQ/H2Q与I2/I3-介质溶液中镀层厚度为1～2μm时,具有较好的光电转换性能,光生电压值最高达358 mV.
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| 关 键 词： | 富勒烯 联萘二苯膦 金属配合物 光伏效应 |
Synthesis and Characterization and Photoelectric Property of Fullerene Complex C60Pt(BINAP) |
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| QIN Shi-Hui,WU Zhen-Yi,YANG Sheng-Yan and ZHAN Meng-Xiong. Synthesis and Characterization and Photoelectric Property of Fullerene Complex C60Pt(BINAP)[J]. Chinese Journal of Inorganic Chemistry, 2008, 24(10): 1626-1630 |
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| Authors: | QIN Shi-Hui WU Zhen-Yi YANG Sheng-Yan ZHAN Meng-Xiong |
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| Affiliation: | College of Chemistry and Chamical Engineering, Xiamen University, Xiamen, Fujian 361005; Department of Chemistry and Life Science, Hechi University, Yizhou, Guangxi 546300,College of Chemistry and Chamical Engineering, Xiamen University, Xiamen, Fujian 361005,College of Chemistry and Chamical Engineering, Xiamen University, Xiamen, Fujian 361005 and College of Chemistry and Chamical Engineering, Xiamen University, Xiamen, Fujian 361005 |
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| Abstract: | |
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| Keywords: | fullerene BINAP matel complexes photoelectric effection |
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