Encapsulation of tetrathiafulvalene inside a dimeric molecular capsule |
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| Authors: | Qiu Yanhua Yi Song Kaifer Angel E |
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| Institution: | Center for Supramolecular Science and Department of Chemistry, University of Miami, Coral Gables, Florida 33124-0431, United States. |
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| Abstract: | Tetrathiafulvalene (TTF) is trapped inside a dimeric capsule formed by two octaacid, deep-cavity cavitands in aqueous solution. While the first one-electron oxidation of TTF is strongly hindered by encapsulation, the capsular assembly is eventually destabilized upon oxidation of the guest. |
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