A perfectly square-planar tetracoordinated oxygen in a tetracopper cluster-based coordination polymer |
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| Authors: | Zhang Xian-Ming Lv Jin Ji Fang Wu Hai-Shun Jiao Haijun Schleyer Paul v R |
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| Institution: | School of Chemistry and Material Science, Shanxi Normal University, Linfen 041004, China. zhangxm@dns.sxnu.edu.cn |
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| Abstract: | A perfectly square-planar, D(4h)-symmetric, tetracoordinated oxygen has been observed in a tetracopper cluster-based coordination polymer that shows an unusual magnetic moment and ESR signal. The stabilization factor of the square-planar tetracoordinated oxygen has been revealed using DFT calculations. |
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