A Highly Stable Nonhysteretic {Cu2(tebpz) MOF+water} Molecular Spring
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| Authors: | Dr Yaroslav Grosu Dr Mian Li Yun‐Lei Peng Dong Luo Prof Dan Li Dr Abdessamad Faik Prof Jean‐Marie Nedelec Prof Jean‐Pierre Grolier |
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| Institution: | 1. Institut de Chimie de Clermont-Ferrand, Universite Clermont Auvergne, SIGMA Clermont, Clermont-Ferrand, France;2. UMR 6296, CNRS, Aubiere, France;3. Laboratory of Thermomolecular Energetics, National Technical, University of Ukraine “Kyiv Polytechnic Institute”, Kyiv, Ukraine;4. CIC Energigune, Mi?ano, álava, Spain;5. Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong, China |
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| Abstract: | A molecular spring formed by a hydrophobic metal–organic framework Cu2(tebpz) (tebpz=3,3′,5,5′‐tetraethyl‐4,4′‐bipyrazolate) and water is presented. This nanoporous heterogeneous lyophobic system (HLS) has exceptional properties compared to numerous reported systems of such type in terms of stability, efficiency, and operating pressure. Mechanical and thermal energetic characteristics as well as stability of the system are discussed and compared in detail with those of other previously reported HLS. |
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| Keywords: | energy conversion heterogeneous lyophobic systems interfaces metal– organic frameworks molecular devices |
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