Biomimetic total syntheses of flinderoles B and C |
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Authors: | Dethe Dattatraya H Erande Rohan D Ranjan Alok |
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Affiliation: | Organic Chemistry Division, National Chemical Laboratory, Pune 411008, Maharashtra, India. dh.dethe@ncl.res.in |
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Abstract: | A simple and efficient biomimetic synthesis of pyrrolo[1,2-a]indoles using a highly stereo- and regioselective [3 + 2] reaction cascade was developed and then further applied in the first total synthesis of flinderoles B and C, which proceeded in 17.2% yield over the longest linear sequence of 11 steps. |
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