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Phototransformations of azetidine radical cations stabilized in freonic matrices |
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| Authors: | I. D. Sorokin V. I. Pergushov L. I. Savostina M. Ya. Melnikov |
| Affiliation: | 1. Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, 119991, Russian Federation 2. Zavoisky Physical-Technical Institute, Kazan Federal University, Kazan, Tatarstan, 420029, Russian Federation |
| Abstract: | It has been established that transformations of azetidine radical cations observed in freonic matrices under the action of light with λ = 436 nm (T = 77 K) are associated with C-N bond cleavage which corresponds to the cyclic form yielding a mixture of open distonic C-centered radical cations of the following structure: ·CH2CH2CH=NH 2 + |
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