Stereoselective intermolecular C-H amination reactions |
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| Authors: | Lebel Hélène Trudel Carl Spitz Cédric |
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| Affiliation: | Département de chimie et Centre en chimie verte et catalyse, Université de Montréal, 2900 Boul. Edouard Montpetit, Montréal, Québec, Canada. helene.lebel@umontreal.ca |
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| Abstract: | A novel chiral N-mesyloxycarbamate to perform rhodium-catalyzed stereoselective C-H amination reactions is reported. Chiral benzylic and propargylic amines are produced in good yields and selectivities using ethyl acetate as solvent. The corresponding free amines are easily obtained by cleavage of the chiral reagent, which could also be recovered. |
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