A pulse radiolysis study of the reactivity of neptunoyl ions relative to inorganic free radicals |
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| Authors: | A. V. Gogolev V. P. Shilov A. M. Fedoseev A. K. Pikaev |
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| Affiliation: | (1) Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions 1. Pulse radiolysis was used to find the rate constants for the reactions of OH, HSO4, NO3, and Cl2 radicals with neptunoyl ions.Change in the NO3 and H+ ion concentrations do not affect the term k[NO3 + NpO2+], while k[Cl2– + NpO2+] increases with increasing chloride concentration due to the formation of neptunoyl ion chlorocomplexes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 456–458, February, 1986. |
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