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A pulse radiolysis study of the reactivity of neptunoyl ions relative to inorganic free radicals
Authors:A V Gogolev  V P Shilov  A M Fedoseev  A K Pikaev
Institution:(1) Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow
Abstract:Conclusions 1. Pulse radiolysis was used to find the rate constants for the reactions of OH, HSO4, NO3, and Cl2 radicals with neptunoyl ions.Change in the NO3 and H+ ion concentrations do not affect the term kNO3 + NpO2 +], while kCl2 + NpO2 +] increases with increasing chloride concentration due to the formation of neptunoyl ion chlorocomplexes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 456–458, February, 1986.
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