Asymmetric synthesis of ageliferin |
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| Authors: | Wang Xiao Ma Zhiqiang Lu Jianming Tan Xianghui Chen Chuo |
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| Affiliation: | Division of Chemistry, Department of Biochemistry, The University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States. |
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| Abstract: | We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the biogenic [4 + 2] dimerization in an intramolecular fashion. |
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