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Chelating ligand conformation driving the hypoxanthine metal binding patterns
Authors:Patel Dheerendra K  Choquesillo-Lazarte Duane  Domínguez-Martín Alicia  Brandi-Blanco M Pilar  González-Pérez Josefa María  Castiñeiras Alfonso  Niclós-Gutiérrez Juan
Institution:Department of Inorganic Chemistry, Faculty of Pharmacy, University of Granada, 18071 Granada, Spain.
Abstract:The X-ray diffraction structural results of 23 ternary compounds, type M(II)(iminodiacetate-like)(hypoxanthine) M = Co, Ni, Cu, or Zn], show that the iminodiacetate moiety conformation (mer-NO(2) or fac-NO(2)) is able to drive the M-hypoxanthine binding patterns displaying the M-N9 or M-N3 bond, cooperating with a N9-H···O intramolecular interaction, respectively.
Keywords:
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