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Asymmetric synthesis of alpha-amino acids: indium-mediated reactions of glyoxylic oxime ether in aqueous media
Authors:Miyabe Hideto  Nishimura Azusa  Ueda Masafumi  Naito Takeaki
Affiliation:Kobe Pharmaceutical University, Motoyamakita, Higashinada, Kobe 658-8558, Japan.
Abstract:The indium-mediated allylation and alkylation reactions of the Oppolzer camphorsultam derivative of glyoxylic oxime ether proceeded with excellent diastereoselectivity in aqueous media, providing a variety of enantiomerically pure alpha-amino acids.
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